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991.
Spreading behaviour of the dimeric surfactant polyethylene-glycoldistearate (PEGDS) monolayer at air/water interface has been
studied using surface pressure-area (π-A) isotherms as a function of temperature. The isotherms show a plateau suggesting
a transition between a liquid expanded (LE) and a condensed state. The condensed state possibly arises due to nucleation and
growth of multilayers from the monolayer. Isobaric measurements of bothA-T and π-T at constant area show transitions atT = 295 K. These plots suggest a melting followed by formation of condensed microcrystallites. Structure optimization carried
out using various angles of orientation of the alkyl tails with respect to the backbone in PEGDS reveals tilt transitions
of the tails in different states which can be related to the packing behaviour seen in the isotherms. Optical microscopy has
been used to confirm the structures in these states. 相似文献
992.
J. Finlay S. Sheppard S. Tookey M. J. Hill P. J. Barham 《Journal of Polymer Science.Polymer Physics》2001,39(12):1404-1414
Young's moduli of a series of quenched isotactic polypropylene/high‐density polyethylene blends were measured. The moduli of many of the blends exceeded the upper bound, calculated from the parallel model with the moduli of the two quenched homopolymers as those of the two components. In fact, both components crystallized at higher temperatures in the blends than they did on their own. It is argued that the higher crystallization temperatures of the components lead to higher component moduli and that this can explain the observation that the measured moduli of the blends apparently exceeded the upper bound. The implications of this work are discussed in light of other studies concerning the measurement and calculation of blend moduli. © 2001 John Wiley & Sons, Inc. J Polym Sci B Part B: Polym Phys 39: 1404–1414, 2001 相似文献
993.
994.
995.
Muriel De Bock Marie-Alice Meuwis Tran Quang Minh Jean-Paul Chapelle Michel Malaise Marianne Fillet 《Talanta》2010,82(1):245-594
In most diseases, the clinical need for serum/plasma markers has never been so crucial, not only for diagnosis, but also for the selection of the most efficient therapies, as well as exclusion of ineffective or toxic treatment. Due to the high sample complexity, prefractionation is essential for exploring the deep proteome and finding specific markers.In this study, three different sample preparation methods (i.e., highly abundant protein precipitation, restricted access materials (RAM) combined with IMAC chromatography and peptide ligand affinity beads) were investigated in order to select the best fractionation step for further differential proteomic experiments focusing on the LMW proteome (MW inferior to 40,000 Da). Indeed, the aim was not to cover the entire plasma/serum proteome, but to enrich potentially interesting tissue leakage proteins. These three methods were evaluated on their reproducibility, on the SELDI-TOF-MS peptide/protein peaks generated after fractionation and on the information supplied.The studied methods appeared to give complementary information and presented good reproducibility (below 20%). Peptide ligand affinity beads were found to provide efficient depletion of HMW proteins and peak enrichment in protein/peptide profiles. 相似文献
996.
LI Ming LI Wei-Hua YANG Xing-Fan PAN Qing XIANG Dao HUANG Wen-Hui TANG Chuan-Xiang LIN Yu-Zheng 《中国物理C(英文版)》2010,34(2)
Magnetic bunch compressor is one of the key technologies on the path to next generation accelerator driven facilities. In this paper we report the design principles and the first experimental research of the bunch compressor developed at Chinese Academy of Engineering Physics (CAEP). The length of the bunch after compressor is found to be about 0.7 ps (rms) and the peak current exceeds 500 A when operated in the optimized condition. The sensitivity of the bunch length on the phase of the acceleration field and magnetic field of the bunch compressor was also measured and analyzed. 相似文献
997.
998.
《Radiation measurements》1999,31(1-6)
The effect α particle fluences (3 × 103−2 × 1015 cm −2) on properties of the two types of phosphate glass detectors with different compositions was studied. It was shown that the registration properties of glass detectors depended on the α particle fluence, spatial distribution of the α particle paths, and glass type. The critical α particle fluences, above which the detector properties changed, were determined. 相似文献
999.
H. KANAYAMA K. TOSHIGAMI Y. TASHIRO M. TABATA S. FUJIMA 《International Journal of Computational Fluid Dynamics》2013,27(1-2):155-162
An upwind finite element scheme for the incompressible viscous flow at a high Reynolds number was proposed by the fourth and fifth authors. The scheme has the potential to approximate the advection term in third-order accuracy. We apply it to a two-dimensional non-stationary analysis of airflows around an Automated Guided Vehicle (AGV), which starts with constant acceleration, runs at a constant speed and stops with constant deceleration. The results are at least qualitatively good and compatible with experimental ones. 相似文献
1000.
Abstract A fully automated high temperature (800 deg C) high pressure (1000 bar) reaction vessel for extremely corrosive media is depicted. 相似文献